Synthesis of novel unsymmetrical phthalocyanines substituted with crown ether and nitro groups |
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Authors: | Yasin Arslanoğlu Atıf Koca Esin Hamuryudan |
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Institution: | 1. Department of Chemistry, Technical University of Istanbul, 34469 Maslak, Istanbul, Turkey;2. Department of Chemical Engineering, Engineering Faculty, Marmara University, 34722 Göztepe, Istanbul, Turkey |
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Abstract: | This work reports on the synthesis of new unsymmetrically substituted phthalocyanines (M = Zn, Cu, Co, Ni) bearing three benzo-15-crown-5 units through oxy bridges and a nitro group. Phthalocyanines were prepared by a statistical condensation of 4-nitro phthalonitrile and 1-{(benzo-15-crown-5)-4′-yl]oxy}phthalonitrile in the presence of anhydrous metal salts. All the target unsymmetrical phthalocyanines were separated by column chromatography and characterized elemental analyses, 1H NMR, IR, mass and UV–Vis spectral data. Electrochemical behaviors of Cu (II) phthalocyanine by cyclic voltammetry and differential pulse voltammetry techniques gave two common phthalocyanine ring reductions and one ring oxidation processes. Peak-to-peak separation of the processes II and III (388 mV) and the measure of gap (1.672 V) between the HOMO and LUMO for the complex, fits a phthalocyanine with electrochemically inactive metal center. |
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Keywords: | Unsymmetrical Metallophthalocyanines Synthesis Cyclic voltammetry |
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