Palladium(II) complexes with S-benzyl dithiocarbazate and S-benzyl-N-isopropylidenedithiocarbazate: Synthesis,spectroscopic properties and X-ray crystal structures |
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| Authors: | Konstantinos Tampouris Silverio Coco Athanasios Yannopoulos Spyros Koinis |
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| Institution: | 1. National and Kapodistrian University of Athens, Department of Chemistry, Laboratory of Inorganic Chemistry, Panepistimiopolis, 15771 Athens, Greece;2. Universitad de Valladolid, Facultad de Ciencias, Departmento de Química Física y Química Inorgánica, 47005 Valladolid, Spain |
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| Abstract: | Two new palladium(II) bis(NS) chelates, bis(S-benzyl dithiocarbazato)palladium(II) (1) and bis(S-benzyl-N-isopropylidenedithiocarbazato)palladium(II) (2), have been prepared and characterized using single-crystal X-ray diffraction and spectroscopic (electronic, IR and NMR) techniques. Complex 1 has a perfectly square planar trans configuration (point group Ci), while complex 2 has a distorted square planar cis configuration. |
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| Keywords: | Palladium(II) complexes NS ligands Schiff bases Dithiocarbazates S-benzyl dithiocarbazate S-benzyl-N-isopropylidenedithiocarbazate |
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