Experimental and computational study on [2,6-bis(3,5-dimethyl-N-pyrazolyl)pyridine]-(dithiocyanato)mercury(II) |
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| Authors: | Raif Kurtaran,Sinem Odabaşıoğlu,Akin Azizoglu,Hü lya Kara,Orhan Atakol |
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| Affiliation: | 1. Department of Chemistry, Faculty of Arts and Sciences, Bal?kesir University, Cagis 10145, Bal?kesir, Turkey;2. Department of Physics, Faculty of Arts and Sciences, Bal?kesir University, Cagis 10145, Bal?kesir, Turkey;3. Department of Chemistry, Faculty of Sciences, University of Ankara, Tando?an 06100, Ankara, Turkey |
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| Abstract: | The mercury complex of 2,6-bis(3,5-dimethyl-N-pyrazolyl)pyridine (bdmpp) has been synthesized and characterized by X-ray diffraction, IR, UV–Vis and TGA–DTA methods. The structure consists of units in which the mercury atom is pentacoordinate with two sulfur and three nitrogen atoms. [Hg(bdmpp)(SCN)2] has a distorted square pyramid geometry. |
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| Keywords: | Crystal structure Pyrazolyl complexes Thiocyanate anion Mercury(II) Thermal analysis DFT PM3 Computational study |
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