Synthesis and characterization of new macrocyclic Schiff base derived from 2,6-diaminopyridine and 1,7-bis(2-formylphenyl)-1,4,7-trioxaheptane and its Cu(II), Ni(II), Pb(II), Co(III) and La(III) complexes |
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| Authors: | Salih Ilhan Hamdi Temel Ismail Yilmaz Memet Şekerci |
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| Affiliation: | 1. Dicle University, Faculty of Education, Department of Chemistry, 21280 Diyarbak?r, Turkey;2. ?stanbul Technical University, Faculty of Arts and Sciences, Department of Chemistry, 23169 ?stanbul, Turkey;3. F?rat University, Faculty of Arts and Sciences, Department of Chemistry, 23169 Elazi?, Turkey |
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| Abstract: | A new macrocyclic ligand, 1,3,5-triaza-2,4:7,8:16,17-tribenzo-9,12,15-trioxacyclooktadeca-1,5-dien (L) was synthesized by reaction of 2,6-diaminopyridine and 1,7-bis(2-formylphenyl)-1,4,7-trioxaheptane. Then, its Cu(II), Ni(II), Pb(II), Co(III) and La(III) complexes were synthesized by template effect by reaction of 2,6-diaminopyridine and 1,7-bis(2-formylphenyl)-1,4,7-trioxaheptane and Cu(NO3)2 · 3H2O, Ni(NO3)2 · 6H2O, Pb(NO3)2, Co(NO3)2 · 6H2O, La(NO3)3 · 6H2O, respectively. The ligand and its metal complexes have been characterized by elemental analysis, IR, 1H and 13C NMR, UV–Vis spectra, magnetic susceptibility, thermal gravimetric analysis, conductivity measurements, mass spectra and cyclic voltammetry. All complexes are diamagnetic and Cu(II) complex is binuclear. The Co(II) was oxidized to Co(III). The comparative electrochemical studies show that the nickel complex exhibited a quasi-reversible one-electron reduction process while copper and cobalt complexes gave irreversible reduction processes in DMSO solution. |
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| Keywords: | Macrocyclic Schiff base Macrocyclic Schiff base complexes 2,6-Diaminopyridine and 1,7-bis(2-formylphenyl)-1,4,7-trioxaheptane |
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