Encapsulating beryllium – Synthesis,characterisation and modelling of a chiral binaphthyldiimine-Be(II) complex |
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| Authors: | Paul G. Plieger Kevin D. John Anthony K. Burrell |
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| Affiliation: | 1. Massey University, Department of Chemistry, Private Bag 11 222, Palmerston North, New Zealand;2. Chemistry Division, MS J582, Los Alamos National Laboratory, Los Alamos, NM 87545, United States |
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| Abstract: | Beryllium has been successfully incorporated into a naphthalene containing Schiff base ligand. Evidence from 9Be and 1H NMR data and model compounds indicate that the ligand completely encapsulates the beryllium cation via tetra-dentate tetrahedral coordination using both phenol and imine donors. Calculated 9Be NMR data at the B3LYP/6-311G+(2d,p) DFT level of theory is in agreement with this conclusion. |
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| Keywords: | Beryllium Encapsulation GIAO DFT Schiff base NMR Complex |
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