Synthesis and characterisation of trisarylphosphine selenides: Further insight into the effect of fluoroalkylation on the electronic properties of trisarylphosphines |
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| Authors: | Dave J Adams James A BennettDaniel Duncan Eric G HopeJonathan Hopewell Alison M StuartAndrew J West |
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| Institution: | Department of Chemistry, University of Leicester, Leicester, LE1 7RH, UK |
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| Abstract: | Variations in the magnitude of the 1JSeP coupling constants for a range of phosphorus(V) selenides allow the efficiency of different spacer groups at insulating the phosphorus centre in triarylphosphines from highly electron-withdrawing perfluoroalkyl groups to be established. |
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| Keywords: | Phosphine Fluorous NMR Selenide |
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