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Indium(III) one-dimensional polymers with pyrazine and pyrazine, 2-carboxylic acid as the spacer molecules
Authors:Christian R. Samanamú  ,Anne F. Richards
Affiliation:Department of Chemistry, Texas Christian University, Sid Richardson Building, Room 450, Fort Worth, TX 76129, United States
Abstract:The reactions of indium(III) chloride tetrahydrate with pyrazine (C4H4N2) and pyrazine, 2-carboxylic acid afford two polymeric frameworks, the structures of which were characterized in the solid state by single crystal analysis. The former is a one-dimensional infinite structure interlinked by the pyrazine spacer, while the latter is a one-dimensional ‘zigzag’ polymeric structure. A dimeric indium(III) pyrazine complex is also reported.
Keywords:Indium   Pyrazine   Frameworks
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