Reassignment of the crystal space group of crystalline Pr[M(CN)6] · 5H2O (M = Cr,Fe, Co) |
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| Authors: | Lin-Ping Zhang Xian-ju Zhou Thomas C.W. Mak Peter A. Tanner |
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| Affiliation: | 1. Key Laboratory of Science and Technology of Eco-Textiles, Ministry of Education, College of Chemistry and Chemical Engineering, Donghua University, Shanghai 200051, PR China;2. Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong S.A.R., PR China;3. Institute of Modern Physics, Chongqing University of Post and Telecommunications, Chongqing 400065, PR China;4. Department of Biology and Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong S.A.R., PR China |
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| Abstract: | Refinement of the X-ray crystal structures of Pr[M(CN)6] · 5H2O (M = Cr, Fe, Co) enables their space group to be reassigned to P63/mmc. Spectral characteristics are reported for M = Cr and the distinction between the pentahydrate and tetrahydrate series is clearly made from assignments of the infrared spectra. |
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| Keywords: | Cyanide bridge Lanthanide ion Bimetallic Crystal structure Vibrational spectra |
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