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Reaction of 2,3-Dimethylmercaptopropionic Acid with Methylene Blue as an Indicator Reaction for the Kinetic Determination of Selenium
Authors:D F Gainutdinova  N V Shirshova  V F Toropova  G K Budnikov  A R Garifzyanov
Institution:(1) Kazan State University, ul. Kremlevskaya 18, Kazan, Tatarstan, 42008, Russia
Abstract:A new indicator reaction between 2,3-dimethylmercaptopropionic acid and Methyl Blue was proposed for the kinetic determination of selenium. The optimal reaction conditions were found. A linear relationship was observed between the induction period and the Se(IV) concentration in the range between 0.9 and 9.6 ng/mL Se. Masking with EDTA and solvent extraction with diethyldithiophosphoric acid can be used for the separation of interfering elements forming complexes with the reagent.
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