| Ni（Ⅱ）,Cu（Ⅱ）,Zn（Ⅱ）的硝酸盐与氟哌酸的固态配合物的 … |
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| 引用本文： | 张秀利,戴玉杰.Ni（Ⅱ）,Cu（Ⅱ）,Zn（Ⅱ）的硝酸盐与氟哌酸的固态配合物的 …[J].光谱学与光谱分析,2000,20(3):333-335. |
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| 作者姓名： | 张秀利 戴玉杰 |
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| 作者单位： | [1]中国科学院上海原子核研究所 [2]石家庄铁道学院基础部 |
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| 摘 要： | 由氟哌酸与Ｎｉ（Ⅱ）、Ｃｕ（Ⅱ）、Ｚｎ（Ⅱ）的硝酸盐合成了三个未见报道的固态配合物，并用元素分析、摩尔电导、红外光谱、热重分析表征了它们的组成和性质。
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| 关 键 词： | 氟哌酸 配合物 合成 表征 镍 铜 锌 硝酸盐 |
Synthesis and characterization of the solid complexes of Ni(II), Cu(II) and Zn(II) nitrates with norfloxacin] |
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| Xiuli ZHANG.Synthesis and characterization of the solid complexes of Ni(II), Cu(II) and Zn(II) nitrates with norfloxacin][J].Spectroscopy and Spectral Analysis,2000,20(3):333-335. |
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| Authors: | Xiuli ZHANG |
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| Institution: | Shanghai Institute of Nuclear Research, Chinese Academy of Sciences, 201800 Shanghai. |
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| Abstract: | Three solid complexes of Ni (II), Cu (II) and Zn (II) nitrates with norfloxacin, having the composition of Ni (NFA)2 (NO3)] NO3.2H2O, Ca (NFA)2] (NO3)2.H2O, Zn (NFA)2 (NO3)] NO3.2H2O, have been synthesized in aqueous solvent. All the isolated complexes have been characterized by elemental analysis, IR spectra, thermogravimetric analysis and molar conductance in methanol. The results show that Ni (Ni (NFA)2) (NO3)] NO3.2H2O, Zn (NFA)2 (NO3)] NO3.2H2O are 1:1 tape electrolytes in methanol, their coordination numbers are all 6. The nitrates of inner boundary are all bidenlate ligands. The complex torming with copper nitrate and norfloxacin is non-electrolyte in methanol, the coordination number is 4. Norfloxacin molecules with inner salt types are all bidenlate ligands. |
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| Keywords: | Norfloxacin Complexes Transition metals |
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