A novel P,O-type phosphorinane ligand for the Suzuki–Miyaura cross-coupling of aryl chlorides |
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| Authors: | Ehsan Ullah James McNulty Al Robertson |
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| Affiliation: | aDepartment of Chemistry and Chemical Biology, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada L8S 4M1;bCytec Canada Inc., PO Box 240, Niagara Falls, Ontario, Canada L2E 6T4 |
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| Abstract: | The Pd-mediated Suzuki–Miyaura cross-coupling of substituted and unsubstituted aryl chlorides with phosphorinane ligands was investigated uncovering an interesting ligand effect. The scope of the most effective 4-hydroxyl-substituted phosphorinane ligand in Suzuki cross-coupling with challenging aryl chlorides is described. |
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