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水稳定的镁掺杂ZnO量子点:一锅法合成及细胞成像应用
引用本文:张立平,吴山,刘丹,万永刚,刘道森. 水稳定的镁掺杂ZnO量子点:一锅法合成及细胞成像应用[J]. 无机化学学报, 2015, 31(8): 1644-1650
作者姓名:张立平  吴山  刘丹  万永刚  刘道森
作者单位:齐齐哈尔医学院医学技术学院, 齐齐哈尔 161006,齐齐哈尔医学院医药研究中心, 齐齐哈尔 161006,齐齐哈尔医学院医药研究中心, 齐齐哈尔 161006,齐齐哈尔医学院医学技术学院, 齐齐哈尔 161006,齐齐哈尔大学通信与电子工程学院, 齐齐哈尔 161006
基金项目:黑龙江省教育厅科学技术研究基金(No.12541910)资助项目。
摘    要:一锅法合成了镁掺杂的ZnO量子点,利用APTES对其进行表面包覆,并采用XRD、TEM、UV-Vis、PL和FTIR等对材料进行了表征。结果表明镁掺杂能明显增强荧光发光强度,在合适的掺杂浓度(30%)下其量子产率由11%增加到33%。通过APTES的表面包覆使镁掺杂的ZnO量子点具有良好的水溶性和荧光稳定性,可用于MCF-7细胞成像研究。

关 键 词:ZnO量子点  镁掺杂  APTES包覆  水稳定性
收稿时间:2015-05-04
修稿时间:2015-07-01

Water-Stable Magnesium-Doped ZnO Quantum Dots: One-Pot Synthesis and Cell Labeling Applications
ZHANG Li-Ping,WU Shan,LIU Dan,WAN Yong-Gang and LIU Dao-Sen. Water-Stable Magnesium-Doped ZnO Quantum Dots: One-Pot Synthesis and Cell Labeling Applications[J]. Chinese Journal of Inorganic Chemistry, 2015, 31(8): 1644-1650
Authors:ZHANG Li-Ping  WU Shan  LIU Dan  WAN Yong-Gang  LIU Dao-Sen
Affiliation:College of Medical Technology, Qiqihar Medical University, Qiqihar, Heilongjiang 161006, China,Research Institute of Medicine & Pharmacy, Qiqihar Medical University, Qiqihar, Heilongjiang 161006, China,Research Institute of Medicine & Pharmacy, Qiqihar Medical University, Qiqihar, Heilongjiang 161006, China,College of Medical Technology, Qiqihar Medical University, Qiqihar, Heilongjiang 161006, China and Communication and Electronic Engineering Institute, Qiqihar University, Qiqihar, Heilongjiang 161006, China
Abstract:A one-pot method was developed for synthesizing Magnesium-doped ZnO quantum dots (QDs) capped with (3-aminopropyl)triethoxysilane (APTES). The as-prepared quantum dots were characterized by XRD, TEM, UV-Vis, FL (fluorescent spectroscopy) and FTIR. The results show that the Mg-doped quantum dots exhibit greatly enhanced luminescent property and their quantum yield is increased from 11% for un-doped ZnO QDs to 33% for Mg-doped ZnO QDs at Mg-doping content of 30%. In addition, aqueous-stability is achieved by capping the Mg-doped ZnO QDs with APTES. The obtained APTES-capped Mg-doped ZnO QDs exhibit excellent water stability and retain visible emissions. The APTES-capped Mg-doped ZnO QDs demonstrate promising applications in MCF-7 cell labeling.
Keywords:ZnO quantum dots  magnesium-doped  APTES-capped  aqueous-stability
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