| 以吡嗪四甲酸为配体的配合物的合成及表征 |
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| 引用本文： | 高洪苓,毕艳霞,张琴琴,崔建中.以吡嗪四甲酸为配体的配合物的合成及表征[J].无机化学学报,2015,31(8):1603-1608. |
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| 作者姓名： | 高洪苓 毕艳霞 张琴琴 崔建中 |
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| 作者单位： | 天津大学理学院化学系, 天津 300072,天津大学理学院化学系, 天津 300072,天津大学理学院化学系, 天津 300072,天津大学理学院化学系, 天津 300072 |
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| 基金项目： | 国家自然科学基金(No.21271137,21473121),教育部先进能源材料化学重点实验室开放基金(南开大学)资助项目。 |
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| 摘 要： | 合成了两种金属配合物{Cu2(pztc)(4,4'-bpy)(H2O)4]·6H2O}n (1),{(H2bpe)Cd(pztc)(H2O)2]·2.5H2O}n (2)(H4pztc=吡嗪-2,3,5,6-四甲酸,bpy=4,4'-联吡啶,bpe=1,2-二(4-吡啶基)乙烯),测定了其晶体结构,并对其进行了红外光谱、荧光光谱和热重分析等表征。两种配合物均为二维层状结构,但其中吡嗪四酸的配位方式不同。配合物2具有蓝色的荧光,最大荧光发射峰在475 nm。测试了配合物1的电子顺磁共振谱,结果显示Cu2+的特征谱带。
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| 关 键 词： | 吡嗪-2 3 5 6-四甲酸 二维结构 荧光光谱 电子顺磁共振 |
| 收稿时间： | 2015/3/19 0:00:00 |
| 修稿时间： | 2015/5/19 0:00:00 |
Syntheses and Characterizations of Two Complexes with Pyrazine-2,3,5,6-tetracarboxylic Acid |
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| GAO Hong-Ling,BI Yan-Xi,ZHANG Qin-Qin and CUI Jian-Zhong.Syntheses and Characterizations of Two Complexes with Pyrazine-2,3,5,6-tetracarboxylic Acid[J].Chinese Journal of Inorganic Chemistry,2015,31(8):1603-1608. |
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| Authors: | GAO Hong-Ling BI Yan-Xi ZHANG Qin-Qin and CUI Jian-Zhong |
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| Institution: | Department of Chemistry, School of Science, Tianjin University, Tianjin 300072, China,Department of Chemistry, School of Science, Tianjin University, Tianjin 300072, China,Department of Chemistry, School of Science, Tianjin University, Tianjin 300072, China and Department of Chemistry, School of Science, Tianjin University, Tianjin 300072, China |
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| Abstract: | Two complexes with pyrazine polycarboxylic acid, namely {Cu2(pztc)(4,4'-bpy)(H2O)4]·6H2O}n (1), {(H2bpe)Cd(pztc)(H2O)2]·2.5H2O}n (2), (H4pztc=pyrazine-2,3,5,6-tetracarboxylic acid, bpe=1,2-bis(4-pyridyl)ethane, 4,4'-bpy=4,4'-bipyridine), have been prepared by modifying the reaction conditions at room temperature and characterized by IR, elemental analysis, thermal gravimetric analysis, fluorescence measurement and single crystal X-ray diffraction analysis. The structures of two complexes are two-dimensional (2D) networks, but H4pztc has different connection modes in 1 and 2. Complex 2 shows good luminescence properties in solid state at room temperature. Electron Paramagnetic Resonance (EPR) spectra of complex 1 is studied. CCDC: 1039147, 1; 1039296, 2. |
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| Keywords: | pyrazine polycarboxylic ligand two-dimensional network fluorescent property electron paramagnetic resonance spectra |
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