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Stereoselective total synthesis of (−)-synrotolide diacetate from d-ribose |
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| Authors: | Palakodety Radha Krishna P. Srinivas Reddy |
| Affiliation: | D-206/B, Discovery Laboratory, Organic Chemistry Division-III, Indian Institute of Chemical Technology, Hyderabad 500 007, Andhra Pradesh, India |
| Abstract: | Stereoselective total synthesis of synrotolide as its diacetate from d-ribose utilizing a diastereoselective Grignard reaction, preferential (Z)-Wittig olefination, asymmetric allylation, and ring closing metathesis as key steps is reported. |
| Keywords: | smallcaps" >D-Ribose Synrotolide diacetate Diastereoselective Grignard reaction Wittig olefination Asymmetric allylation Ring closing metathesis |
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