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Universal equivalent circuit of electrochemical cell
Authors:N A Sekushin
Institution:(1) Institute of Chemistry of Komi, Scientific Center, Ural Division, Russian Academy of Sciences, Pervomaiskaya 48, Syktyvkar, Russia
Abstract:A detailed analysis of the mathematical model of a random-structure RC two-terminal network is performed. It is shown that a circuit of any RC two-terminal network can be reduced to a universal form consisting of a set of parallel branches. Each branch corresponds to a single relaxation process and represents a circuit of serially connected resistance and capacitor. The equivalent circuit under consideration is a compact representation of experimental data obtained using the impedance spectroscopy method. It is recommended to use the universal circuit as an intermediate model of an electrochemical cell.
Keywords:equivalent circuit  mathematical model  two-terminal network  impedance spectroscopy  relaxation
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