| 配合物Cu(C14H9NO3)(C3H4N2)的合成、晶体结构及性质研究 |
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| 引用本文： | 高山,施展,华佳,冯守华,徐如人,刘世雄,霍丽华,陈鹏刚.配合物Cu(C14H9NO3)(C3H4N2)的合成、晶体结构及性质研究[J].高等学校化学学报,2000,21(2):177-180. |
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| 作者姓名： | 高山 施展 华佳 冯守华 徐如人 刘世雄 霍丽华 陈鹏刚 |
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| 作者单位： | 1. 吉林大学化学系, 教育部无机合成与制备化学开放研究实验室, 长春 130023;
2. 福州大学化学系, 福州 350002;
3. 黑龙江大学化学系, 哈尔滨 150080 |
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| 基金项目： | 中国科学院资助项目，教育部实验室基金，29731010，，， |
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| 摘 要： | 合成了配合物Cu(C14H9NO3)(C3H4N2)C14H9NO32- 为N-(2-羧基苯基)-水杨醛亚胺,C3H4N2为咪唑].晶体属正交晶系,空间群Pca21,晶胞参数a=0.94453(12)nm,b=1.12278(9)nm,c=2.9123(4)nm,V=3.0885(6)nm3,Mr=370.84,Z=8,最终的偏离因子R=0.036,wR=0.087,GOF=0.975.三齿Schiff碱配体中的二个氧原子、一个氮原子和咪唑的一个氮原子与铜原子配位,形成扭曲的平面正方形结构.通过元素分析,IR,UV,CV和TG表征了配合物的结构.
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| 关 键 词： | 铜配合物 Schiff碱 咪唑 晶体结构 |
| 收稿时间： | 1999-06-21 |
Synthesis, Crystal Structure and Characterization of Complex Cu(C14H9NO3)(C3H4N2) |
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| GAO Shan,SHI Zhan,HUA Jia,FENG Shou-Hua,XU Ru-Ren,LIU Shi-Xiong,HUO Li-Hua,CHEN Peng-Gang.Synthesis, Crystal Structure and Characterization of Complex Cu(C14H9NO3)(C3H4N2)[J].Chemical Research In Chinese Universities,2000,21(2):177-180. |
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| Authors: | GAO Shan SHI Zhan HUA Jia FENG Shou-Hua XU Ru-Ren LIU Shi-Xiong HUO Li-Hua CHEN Peng-Gang |
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| Institution: | 1. Department of Chemistry, Key Laboratory of Inorganic Synthesis & Preparative Chemistry of Educational Ministry, Jilin University, Changchun 130023, China;
2. Department of Chemistry, Fuzhou University, Fuzhou 350002, China;
3. Department of Chemistry, Heilongjiang University, Harbin 150080, China |
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| Abstract: | The copper(Ê) complex with N-(2-carboxyphenyl)salicylidenamine and imidazole ligands, Cu(C14H9NO3)(C3H4N2) , was synthesized. The crystal belongs to orthorhombic, space group Pca21, with the crystal cell parameters: a=0.94453(12) nm, b=1.12278(9) nm, c=2.9123(4) nm, V= 3.0885(6) nm3, Mr=370.84, Z=8, R=0.036, wR=0.087, GOF=0.975. The copper(Ê) ion lies in a distorted square-planar environment composed of two oxygen atoms, one nitrogen atom of the tridentate Schiff base ligand and one nitrogen atom of the imidazole ligand. The complex was also characterized by elementary analysis, IR, UV-Vis, TGand cycle voltammetry measurement. |
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| Keywords: | Copper(Ê ) complex Schiff base Imidazole Crystal structure |
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