Chloropolyfluorodiethyl ethers |
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| Authors: | Paul L. Coe Martin S. Lennard John Colin Tatlow |
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| Affiliation: | School of Chemistry, University of Birmingham, Edgbaston Birmingham B15 2TT UK |
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| Abstract: | Fluorination of 2-chlorodiethyl ether by cobalt trifluoride at 110–150 °C afforded isomers of 2-chloro-pentafluoro-, -hexafluoro-, and -heptafluorodiethyl ethers. Chlorine was lost in similar fluorinations of 2-chloro-2,2-difluoroethyl ethyl ether, the only products isolated being a heptaand a hexa-fluoro diethyl ether. Structures were established spectroscopically. |
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| Keywords: | Chloropolyfluorodiethyl ethers Cobalt trifluoride fluorination |
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