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Au纳米颗粒织构化表面的黏着和摩擦学行为研究
引用本文:张晓亮,钟小华,易戈文,贾均红. Au纳米颗粒织构化表面的黏着和摩擦学行为研究[J]. 摩擦学学报, 2010, 30(6): 607-613
作者姓名:张晓亮  钟小华  易戈文  贾均红
作者单位:1. 中国科学院兰州化学物理研究所,固体润滑国家重点实验室,甘肃兰州,730000;中国科学院,研究生院,北京,100049
2. 中国科学院兰州化学物理研究所,固体润滑国家重点实验室,甘肃兰州,730000;兰州理工大学,石油化工学院,甘肃,兰州,730050
3. 中国科学院兰州化学物理研究所,固体润滑国家重点实验室,甘肃兰州,730000
基金项目:国家自然科学基金项目(50705094,50972148)和中国科学院百人计划项目(KGCX2-YW-804)
摘    要:利用自组装技术在单晶硅(100)面制备了Au纳米颗粒织构化表面(nanoparticle-textured surfaces,NPTS),采用原子力显微镜(AFM)和UMT-2MT摩擦磨损试验机考察了Au纳米颗粒织构化对表面微/纳尺度黏着与摩擦性能的影响机理.结果表明:在颗粒堆积密度较低的表面,接触力学符合连续接触力学模式;在颗粒堆积密度较高的表面,形成多峰接触,有效地减少了接触面积,降低了黏着和摩擦.与光滑硅表面相比,组装时间为3.0 h的Au纳米颗粒织构化表面的黏着力降低了77%,在试验载荷为7 nN时,其摩擦力降低了42%.

关 键 词:纳米织构化;自组装单层膜(SAMs);摩擦性能
收稿时间:2010-05-04

Adhesive and Frictional Properties of AuNanoparticle-textured Surfaces
ZHANG Xiao-liang,ZHONG Xiao-hu,YI Ge-wen and JIA Jun-hong. Adhesive and Frictional Properties of AuNanoparticle-textured Surfaces[J]. Tribology, 2010, 30(6): 607-613
Authors:ZHANG Xiao-liang  ZHONG Xiao-hu  YI Ge-wen  JIA Jun-hong
Affiliation:1. State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China2. Graduate University of Chinese Academy of Sciences, Beijing 100049, China;1. State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China2. Lanzhou University of Technology, Lanzhou 730050, China;State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China;State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
Abstract:Au nanoparticle-textured surfaces were prepared on the silicon (100) surfaces by using the self-assembly techniques. The atomic force microscope (AFM) and UMT-2MT tribometer were used to examine the adhesion and friction mechanisms in micro-/nano-scales of nanoparticle-textured surfaces. The results showed that: in textured surfaces with low texture densities, the continuum contact mechanics model was found to be applicable to the surface contact between the tip and the textured surfaces in nano-scale. While in the higher texture density surfaces, the surface contact mechanic between the tip and Au nanoparticle-textured surfaces followed the multi-asperity contact model which effectively reduced the contact area, accordingly reducing the adhesion and friction. Compared with the smooth surface of silicon, the adhesion force of the Au NPTS at assembling time of 3.0 h was reduced by 77%, and the friction force of the Au NPTS at assembling time of 3.0 h was reduced by 42% under the normal load of 7 nN.
Keywords:nano texture   self-assembly monolayers (SAMs)   friction behavior
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