Mechanically driven reorganization of thermoresponsive diblock copolymer assemblies in water |
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| Authors: | Kessel Stefanie Urbani Carl N Monteiro Michael J |
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| Affiliation: | Australian Institute for Bioengineering and Nanotechnology, The University of Queensland, Brisbane QLD 4072 (Australia). |
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| Abstract: | Controlled formation of a variety of 3D structures was observed at high polymer weight fractions in water from a single diblock, consisting of poly(N-isopropylacrylamide), PNIPAM, and polystyrene, PSTY segments. The structures form through a mechanical process driven by swelling of hydrophilic polymer segments upon a change in temperature (see picture, SDS=sodium dodecylsulfate). |
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| Keywords: | living radical polymerization nanostructures polymers self‐assembly |
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