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Studies on the extraction and determination of metals-I Extraction of hafnium into methyl isobutyl ketone and tributyl phosphate
Authors:Ichinose N
Institution:

Department of Chemistry Faculty of Liberal Arts Yamaguchi University Yamaguchi, Japan

Abstract:The effect of various factors on the distribution of hafnium (less-than-or-equals, slant 5.60 × 10?4M) between different acids and methyl isobutyl ketone (MIBK) or tributyl phosphate (TBP) was studied by using 176 + 181 Hf as a tracer, when the extraction is made from 7.5–11M hydrochloric acid with an equal volume of IM TBP in benzene, hafnium is extracted quantitatively (>99%). The hafnium can be stripped with 1–3M hydrochloric acid.
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