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Compositions of the condensed medium and gas phase forming upon heating of uranium oxides (UO2, UO3, U3O8, and U4O9) in argon and oxygen atmosphere: Computer experiment
Authors:G K Moiseev  A B Shubin  T V Kulikova and A L Ivanovskii
Institution:(1) Institute of Metallurgy, Ural Division, Russian Academy of Sciences, ul. Amundsena 101, Yekaterinburg, 620016, Russia;(2) Institute of Solid-State Chemistry, Ural Division, Russian Academy of Sciences, ul. Pervomaiskaya 91, Yekaterinburg, 620219, Russia
Abstract:Thermodynamic modeling methods have been used for calculating the compositions of the condensed medium and gas phase forming upon heating of the oxides UO2, UO3, U3O8, and U4O9 at constant pressure (p = 0.1 MPa) in the temperature range 300–2000 K in an inert (Ar) or oxidative (O2) atmosphere. The stability of uranium oxides and the state of aggregation of the condensed medium have been studied as a function of temperature. Original Russian Text ? G.K. Moiseev, A.B. Shubin, T.V. Kulikova, A.L. Ivanovskii, 2008, published in Zhurnal Neorganicheskoi Khimii, 2008, Vol. 53, No. 6, pp. 985–989.
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