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[Ir(COD)Cl]2/tris(2,4-di-t-butylphenyl)phosphite-catalyzed addition reactions of arylboronic acids with aldehydes
Authors:Yuan-Xi Liao  Jie Dong  Qiao-Sheng Hu
Affiliation:Department of Chemistry, College of Staten Island of the City University of New York, Staten Island, New York 10314, United States;The Ph.D. Program in Chemistry, The Graduate Center of the City University of New York, New York, NY 10016, United States
Abstract:[Ir(COD)Cl]2/tris(2,4-di-t-butylphenyl)phosphite-catalyzed addition reactions of arylboronic acids with aldehydes were described. The Ir(I) catalyst, generated from [Ir(COD)Cl]2 and tris(2,4-di-t-butylphenyl)phosphite, was an efficient catalyst system for the addition reactions of a variety of arylboronic acids with aromatic and aliphatic aldehydes. The easy availability of the catalyst and good yields make these reactions potentially useful in organic synthesis.
Keywords:Iridium(I)  Phosphite  Arylboronic acids  Aldehydes  Addition reactions
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