[Ir(COD)Cl]2/tris(2,4-di-t-butylphenyl)phosphite-catalyzed addition reactions of arylboronic acids with aldehydes |
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Authors: | Yuan-Xi Liao Jie Dong Qiao-Sheng Hu |
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Affiliation: | Department of Chemistry, College of Staten Island of the City University of New York, Staten Island, New York 10314, United States;The Ph.D. Program in Chemistry, The Graduate Center of the City University of New York, New York, NY 10016, United States |
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Abstract: | [Ir(COD)Cl]2/tris(2,4-di-t-butylphenyl)phosphite-catalyzed addition reactions of arylboronic acids with aldehydes were described. The Ir(I) catalyst, generated from [Ir(COD)Cl]2 and tris(2,4-di-t-butylphenyl)phosphite, was an efficient catalyst system for the addition reactions of a variety of arylboronic acids with aromatic and aliphatic aldehydes. The easy availability of the catalyst and good yields make these reactions potentially useful in organic synthesis. |
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Keywords: | Iridium(I) Phosphite Arylboronic acids Aldehydes Addition reactions |
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