Phosphinate selective hosts and importance of C H hydrogen bonding for affinity modulation toward anion guests |
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Authors: | Dae Hyup Sohn Eunbi Han Seung Joo Cho Jongmin Kang |
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Institution: | 1. Department of Chemistry, Sejong University, Seoul 143-747, South Korea;2. Department of Cellular and Molecular Medicine, College of Medicine, Chosun University, 375 Seosuk-dong, Dong-gu, Gwangju 501-759, South Korea |
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Abstract: | Even though phosphinate and its analogs are very important guests in nature, the artificial receptors which are capable of selective recognition of phosphinate are rare. Here, we report a series of acetate and phosphinate selective hosts (1, 2 and 3) which utilize amide N![/>H and aliphatic C<img style=](https://sdfestaticassets-us-east-1.sciencedirectassets.com/prod/dfcf6ffc10ef1f214ae15002a0bf0d0980d00cf9/entities/sbnd) | |
Keywords: | Phosphinate selective host Anion recognition Anion receptor design |
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