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Phosphinate selective hosts and importance of CH hydrogen bonding for affinity modulation toward anion guests
Authors:Dae Hyup Sohn  Eunbi Han  Seung Joo Cho  Jongmin Kang
Institution:1. Department of Chemistry, Sejong University, Seoul 143-747, South Korea;2. Department of Cellular and Molecular Medicine, College of Medicine, Chosun University, 375 Seosuk-dong, Dong-gu, Gwangju 501-759, South Korea
Abstract:Even though phosphinate and its analogs are very important guests in nature, the artificial receptors which are capable of selective recognition of phosphinate are rare. Here, we report a series of acetate and phosphinate selective hosts (1, 2 and 3) which utilize amide N/>H and aliphatic C<img style=
Keywords:Phosphinate selective host  Anion recognition  Anion receptor design
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