Silver-mediated radical aryltrifluoromethylthiolation of activated alkenes by S-trifluoromethyl 4-methylbenzenesulfonothioate |
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| Authors: | Xia Zhao Bo Yang Aoqi Wei Jianqiao Sheng Miaomiao Tian Quan Li Kui Lu |
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| Institution: | 1. College of Chemistry, Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Key laboratory of Inorganic-organic Hybrid Functional Material Chemistry, Ministry of Education, Tianjin Normal University, Tianjin 300387, China;2. College of Biotechnology, Tianjin University of Science & Technology, Tianjin 300457, China |
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| Abstract: | Herein, we describe the preparation of trifluoromethylthiol-substituted oxindoles by silver-mediated aryltrifluoromethylthiolation of activated alkenes, using S-trifluoromethyl 4-methylbenzenesulfonothioate as a F3CS radical source and showing that the reagent availability, mild conditions, and broad functional group compatibility of this transformation make it a viable alternative strategy of constructing Csp3 | |
| Keywords: | Silver-mediated Radical Aryltrifluoromethylthiolation Activated alkenes Oxindole |
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