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Chemoselective oxidation and deprotection of para-methoxybenzylic position with (diacetoxyiodo)benzene in acetic-trifluoroacetic acid
Authors:Chun-Yu Lin  Ping-Shin Yang  Pang-Yu Chou  Chi Wi Ong
Affiliation:Department of Chemistry, National Sun Yat Sen University, Kaohsiung 804, Taiwan
Abstract:(Diacetoxyiodo)benzene in the presence of acetic–trifluoroacetic acid in THF has been developed for the chemoselective para-methoxybenzylic C/>H bond oxidation to provide aryl carbonyl compounds at room temperature. The reaction condition is also applicable for the chemoselective deprotection of <em>para</em>-methoxybenzyl (PMB) ether in the presence of benzyl ether.</td>
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Keywords:(Diacetoxyiodo)benzene  Corresponding author.
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