Recent advances of hexaazatriphenylene (HAT) derivatives: Their applications in self-assembly and porous organic materials |
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Authors: | Xiao-Yang Yan Meng-Di Lin Si-Tai Zheng Tian-Guang Zhan Xiang Zhang Kang-Da Zhang Xin Zhao |
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Institution: | 1. Xinzhi College of Zhejiang Normal University, College of Chemistry and Life Science, Zhejiang Normal University, 688 Yingbin Road, Jinhua 321004, China;2. Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China;3. School of Chemical Engineering, Hunan Chemical Vocational College of Technology, 1 Zhihui Road, Zhuzhou 412000, China |
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Abstract: | As a rigid and planar aza-based heteroaromatic scaffold, hexaazatriphenylene (HAT) exhibits excellent electron-deficient property and high π-π stacking tendency, which makes it an ideal building block in the construction of supramolecular architectures and functional materials. In addition, HATs have also been picked out as building blocks for the construction of novel porous organic polymers, one of the most attractive fields of porous materials in the past decade, which includes intrinsic microporosity (PIMs), π-conjugated microporous polymers (CMPs), and covalent organic frameworks (COFs). In this digest paper, the synthetic methods of HAT derivatives have been briefly introduced and some recent advances of HATs in the applications of supramolecular self-assembly and porous organic materials have been highlighted. |
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Keywords: | Hexaazatriphenylene Synthesis Self-assembly Porous organic materials Covalent organic frameworks |
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