CuI catalyzed-novel one-pot synthesis of aryl alkenyl thioethers through Ullmann-type coupling reactions using carbon disulfide as a sulfur surrogate in the presence of nitroalkanes and aryl iodides |
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| Authors: | Mehdi Adib Vahideh Sadeghi Hojat Veisi |
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| Affiliation: | 1. School of Chemistry, University College of Science, University of Tehran, P.O. Box 14155-6455 Tehran, Iran;2. Department of Chemistry, Payame Noor University (PNU), Tehran, Iran |
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| Abstract: | A mild, general and efficient copper-catalyzed system for C-S bond formation is developed. With CuI as catalyst and l-Proline as ligand, the S-arylation of nitroalkane-CS2 adducts with aryl iodides were performed under mild conditions to give the corresponding products in good to excellent yields. |
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| Keywords: | Copper(I) iodide Ullmann-type coupling S-arylation Corresponding authors. |
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