An extension of nickel-catalyzed reductive coupling between tertiary alkyl halides with allylic carbonates |
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| Authors: | Yingying Yu Haifeng Chen Qun Qian Ken Yao Hegui Gong |
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| Institution: | 1. Department of Chemistry, Shanghai University, 99 Shang-Da Road, Shanghai 200444, China;2. School of Materials Science and Engineering, Shanghai University, China |
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| Abstract: | The nickel catalyzed reductive coupling of allylic carbonates with chloro-cyclotryptamine analogs to construct sterically congested all C(sp3) quaternary centers has been achieved with emphasis on the substrate scope. And the using of dienyl methyleneyl carbonates coupling with a variety of tertiary alkyl halides furnished the dienylated products improved the reaction's applicability. |
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| Keywords: | Allylation Chloro-cyclotryptamine Nickel catalyzed Extension Dienyl carbonate |
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