Regio- and stereospecific synthesis of dl-4,5-dibromo-4,5-dideoxy-3,6-O-methyl-chiro-inositol |
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| Authors: | Latif Kelebekli Kadir Aksu Ertan ?ahin |
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| Institution: | 1. Department of Chemistry, Ordu University, 52200 Ordu, Turkey;2. Department of Chemistry, Ataturk University, 25240 Erzurum, Turkey |
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| Abstract: | The regio- and stereospecific synthesis of dl-4,5-dibromo-4,5-dideoxy-3,6-O-methyl-chiro-inositol is reported. Bromination of p-benzoquinone followed by reduction of the carbonyl groups with NaBH4 gave the corresponding trans-dibromodiol compound, which was reacted with sodium methoxide to produce dimethoxy conduritol-B. Regiospecific bromination of the alkene moiety furnished the desired chiro-inositol derivative. |
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| Keywords: | Methoxy conduritol-B Methoxy inositol Regio- and stereospecific synthesis |
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