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Radiohochspannungsionophoretische Untersuchungen der Isotopenaustauschreaktionen zwischen Polythionaten,Thiosulfat und Sulfit
Authors:H Wagner  H Schreier
Institution:1. Fachrichtung Anorganische Analytik und Radiochemie der Universit?t des Saarlandes, 6600, Saarbrücken, BRD
Abstract:The isotopic exchange of35S between thiosulfate/sulfite and tetrathionate/thiosulfate is examined. The kinetic data are determined. In both cases the reactions are of second order. As the isotopic exchange between tetrathionate/thiosulfate is very fast, these reaction components are used in high dilution. Furthermore, the extent of exchange during the separation is determined.
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