The ketene thioacetal group as a cationic cyclization terminator. : A synthesis of the pyrrolizidine ring system. |
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Authors: | A.Richard Chamberlin John Y.L. Chung |
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Affiliation: | Department of Chemistry, University of California Irvine, California 92717 U.S.A. |
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Abstract: | A cationic cyclization to the pyrrolizidine ring system is reported in which a ketene thioacetal group serves as an efficient terminator for 5-membered ring formation. (±)-Supinidine is prepared using this methodology. |
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