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The ketene thioacetal group as a cationic cyclization terminator. : A synthesis of the pyrrolizidine ring system.
Authors:A.Richard Chamberlin  John Y.L. Chung
Affiliation:Department of Chemistry, University of California Irvine, California 92717 U.S.A.
Abstract:A cationic cyclization to the pyrrolizidine ring system is reported in which a ketene thioacetal group serves as an efficient terminator for 5-membered ring formation. (±)-Supinidine is prepared using this methodology.
Keywords:
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