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Synthesis and absolute configuration of +-lineatin,the pheromone of trypodendronlineatum
Authors:Kenji Mori  Tamon Uematsu  Masao Minobe  Kazunori Yanagi
Institution:Department of Agricultural Chemistry, The University of Tokyo, Yayoi, 1-1-1, Bunkyo-ku, Tokyo 113 Japan;Central Research Laboratory, Sumitomo Chemical Co., Tsukahara 2–40, Takatsuki-shi, Osaka 569, Japan
Abstract:A new synthesis of (±), (+)- and (-)-lineatin (3,3,7-trimethyl-2, 9-dioxatricyclo 3.3.1.04,7] nonane, 1) was achieved. The stereochemistry of (+)-lineatin was established as 1R, 4S, 5R, 7R by an X-ray crystallographic analysis of an intermediate 15.
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