Sirodesmin A: Synthesis of a chiral left half. |
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| Authors: | William H. Rastetter Julian Adams Jon Bordner |
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| Affiliation: | Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 U.S.A.;Department of Chemistry, North Carolina State University, Raleigh, North Carolina 27650 U.S.A. |
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| Abstract: | A stereoselective and chiral synthesis of a precursor to the fungal metabolite sirodesin A () is described. The correct relative and absolute confirugation for intermediate (Scheme 1) is established in a single, highly enantioselective epoxidation. |
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