|
|||||
|
|
Generation and reactivity of sterically hindered bicyclo[3.1.0]hex-1-enes |
|
| Authors: | Richard F Salinaro Jerome A Berson |
| Institution: | Department of Chemistry, Yale University, P.O. Box 666, New Haven, CT 06511 U.S.A. |
| Abstract: | 2-t-butylbicyclo3.1.0]hex-1-ene dimerizes primarily by a σ+ π] way, whereas 2,5-di-t-butylbicyclo3.1.0]hex-1-ene undergoes an unusual hydrogen shift reaction to 1,3-di-t-butyl-2-methylcyclopentadiene. |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ | |