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Ru-catalyzed oxidation of substituted acetylenes to α-keto esters and α-keto amides with iodosylbenzene |
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| Authors: | Paul Müller José Godoy |
| Institution: | Department de Chimie Organique, Université de Genèva, 1211 Genèva 4, Switzerland |
| Abstract: | Oxidation of alkynyl ethers and -amines with iodosylbenzene in presence of Ru-catalysts affords α-keto esters and α-keto amides in 44–85% yield. These conversions can also be effected with RuO4. |
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