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Transmission of polar substituent effects in bicycloalkane systems as probed by fluorine-19 nuclear magnetic resonance
Authors:William Adcock  Anil N. Abeywickrema  Gaik B. Kok
Affiliation:School of Physical Sciences, The Flinders University of South Australia, Bedford Park, S.A., 5042 AUSTRALIA
Abstract:The results of a correlative analysis indicate that the 19F substituent chemical shifts (SCS) of 4-substituted bicyclo[2.2.1]hept-1-y1 fluorides are essentially a manifestation of electronegativity effects which are opposite in sign to those previously disclosed for the corresponding 4-substituted bicyclo[2.2.2]oct-1-y1 fluorides.
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