Transmission of polar substituent effects in bicycloalkane systems as probed by fluorine-19 nuclear magnetic resonance |
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Authors: | William Adcock Anil N. Abeywickrema Gaik B. Kok |
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Affiliation: | School of Physical Sciences, The Flinders University of South Australia, Bedford Park, S.A., 5042 AUSTRALIA |
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Abstract: | The results of a correlative analysis indicate that the 19F substituent chemical shifts (SCS) of 4-substituted bicyclo[2.2.1]hept-1-y1 fluorides are essentially a manifestation of electronegativity effects which are in sign to those previously disclosed for the corresponding 4-substituted bicyclo[2.2.2]oct-1-y1 fluorides. |
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