Regio- and stereoselective synthesis of -1,3-enynes via coupling of nucleophiles with 1-[(alkynyl) dicobalt hexacarbonyl]allyl cations |
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| Authors: | S Padmanabhan KM Nicholas |
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| Institution: | Chemistry Department Boston College Chesnut Hill, MA 02167 U.S.A. |
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| Abstract: | Reactions of the title complexes with the nucleophiles anisole, allyl silanes, isopropenyl acetate, and ethanol have been examined. The carbon nucleophiles react regio- and stereoselectively to give -1,3-enyne derivatives. |
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