Biomimetic oxidation of organic sulfides with TPPFe(III)Cl/imidazole/hydrogen peroxide |
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| Authors: | Shigeru Oae Yoshihito Watanabe Ken Fujimori |
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| Affiliation: | Department of Chemistry, The University of Tsukuba, Sakura-mura, Ibaraki 305, Japan |
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| Abstract: | An enzyme model system, consisted with TPPFe(III)Cl/imidazole has been found to catalyze hydrogen peroxide dependent S-oxygenation and oxidative S-dealkylation of organic sulfides. This biomimetic reaction has been compared with the cytochrome P-450 catalyzed H2O2 dependent oxygenation. |
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