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Mechanism of isomerization of ortho or para bromo phenols in superacids
Authors:Jean-Claude Jacquesy  Marie-Paule Jouannetaud
Abstract:In superacids ortho or para bromo phenols are isomerized into the meta bromo isomers. In SbF5-HF, the process is intramolecular and proceeds by a 1,2-Br shift. In CF3SO3H, the mechanism involves loss of bromine, followed by meta bromination.
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