Cyclopropyl halides. Electron transfer in the lithium aluminum hydride reduction of dibromo and monobromocyclopropanes. |
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| Authors: | Michael A McKinney Steve W Anderson Michael Keyes Ronald Schmidt |
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| Institution: | Department of Chemistry, Marquette University, Milwaukee, Wisconsin 53233 U.S.A. |
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| Abstract: | The stereochemistry of reduction of mixtures of r-1-bromo-1-deuterio-c- and t-2-phenylcyclopropane and the cyclized products from 1,1-dibromo-2-(3-butenyl cyclopropane upon reduction with lithium aluminum hydride give evidence of a configurationally equilibrated cyclopropyl radical as a reaction intermediate. |
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