Efficient preparation of allylic grignard reagents using slurries of precondensed magnesium |
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| Authors: | Wolfgang Oppolzer Ernest Peter Kündig Paul M. Bishop Celia Perret |
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| Affiliation: | Département de Chimie Organique, Université de Genève, CH-1211 Genève, Switzerland |
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| Abstract: | Using a simple apparatus addition of 2-alkenyl halides to precondensed active Mg in THF gave clean solutions of 2-alkenylmagnesium halides which on carbonation furnished β,γ-unsaturated carboxylic acids in high yields. |
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