Dihydrosilaanthracenylidene and dihydroanthracenylidene |
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| Authors: | Akira Sekiguchi Wataru Ando Tadashi Sugawara Hiizu Iwamura Michael TH Liu |
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| Institution: | Department of Chemistry, The University of Tsukuba, Niiharigun, Ibaraki 305, Japan;The Institute for Molecular Science, 38 Nishigonaka, Okazaki 444, Japan;Department of Chemistry, University of Prince Edward Island, Charlottetown, Prince Edward Island, Canada |
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| Abstract: | Carbenes generated from 10-diazo-9,9-dimethyl-9,10-dihydro-9-silaanthracene and 10-diazo-9,9-dimethyl-9,10-dihydroanthracene gave hydrogen abstraction products by the triplet nature of these carbenes. The triplet dihydrosilaanthracenylidene was shown by the electron spin resonance study. |
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