An isomerization—claisen rearrangement route to olefinic dicarbonyl starting materials for conjugate cyclization |
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Authors: | Gilbert Stork Karnail S Atwal |
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Institution: | Department of Chemistry, Columbia University New York, New York 10027 U.S.A. |
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Abstract: | Unsaturated dicarbonyl compounds which are useful in conjugate cyclization processes are synthesized by a route which makes use of a sequential isomerization and Claisen rearrangement of the allyl ether of a substituted allyl alcohol. |
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