Non-planar axial Me2N in <math><mtext>cis</mtext></math>-2-dimethylamino-2-thio-5-<math><mtext>t</mtext></math>-butyl-1,3,2-oxazaphosphorinane期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Non-planar axial Me₂N in $cis$ -2-dimethylamino-2-thio-5- $t$ -butyl-1,3,2-oxazaphosphorinane

Authors:	M.Gary Newton Nantelle Pantaleo Wesley G. Bentrude S. Chandrasekaran

Affiliation:	Department of Chemistry, University of Georgia, Athens, Georgia 30602 U.S.A.;Department of Chemistry, University of Utah, Salt Lake City, Utah 84112 U.S.A.

Abstract:	An X-ray crystallographic study of the title compound shows it to have an axial Me₂N with pyramidal N and a lengthened N-P bond. Conversely, the endocyclic NH-P bond is shortened. The origins of these effects are assigned to specific geometrical relationships of the Me₂N/P=S and NH/P=S groupings imposed by the ring system.

Keywords:
本文献已被 ScienceDirect 等数据库收录！