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Highly diastereoselective oxidations of a thioether appended with a neighboring hydroxyl group
Authors:Richard S. Glass  William N. Setzer  Usha Devi G. Prabhu  George S. Wilson
Affiliation:Department of Chemistry, The University of Arizona, Tucson AZ 85721 USA
Abstract:Highly diastereoselective oxidations of endo-alcohol 1 to the corresponding sulfoxides, the relative stereochemistries of these sulfoxides and that of an intermediary alkoxysulfonium salt determined by X-ray crystallographic analysis is reported.
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