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Reactions of aminophosphines with trifluormethanesulfonic acid: phosphenium ion (two-coordinate phosphorus ion) or tricovalent phosphorus products?
Authors:Otto Dahl
Affiliation:Department of General and Organic Chemistry, The H. C. Ørsted Institute, University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen, Denmark
Abstract:The title reaction is shown to give phosphenium ion products (1), mixtures of (10 and tricovalent substitution products (2), or other products, depending on the nature of the substituents on phosphorus.
Keywords:
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