Carbon-alkylation,arylation and vinylation of nitronate ions with organothallium(III) compounds: electron-transfer activation of the TlC bond |
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Authors: | Hideo Kurosawa Masahiro Sato Hiroshi Okada |
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Institution: | Department of Petroleum Chemistry, Osaka University, Suita, Osaka, Japan |
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Abstract: | The reaction of alkyl, aryl and vinylthallium(III)_diacetates with nitronate ions gives moderate to good yields of the carboncarbon bonded products. The reaction of the alkyl and arylthallium(III) analogs proceeds through radical intermediates which are generated by electron-transfer activation of the thalliumcarbon bond. |
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