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Synthesis and properties of a bridged phenalenone incorported into bicyclo[3.2.2]nonane skeleton. 6,9-dihydro-6,9-ethenocyclohepta[gh]phenalen-1-one
Authors:Yoshikazu Sugihara  Katsuhiro Hashimoto  Masahiro Yoshiakwa  Ichiro Murata
Institution:Department of Chemistry, Faculty of Science, Osaka University, Toyonaka, Osaka 560, Japan
Abstract:6,9-Dihydro-6,9-ethenocycloheptagh]phenalen-1-one (1) has been synthesised starting from the Diels-Alder adduct (6) of acepleiadiene (5) and maleic anhydride through 10 steps with reasonable yields. Spectroscopic properties of 1 suggestged the intramolecular electron supply from the remote ethylenes to the phenalenone π-systems in the ground-state of this molecule.
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