Synthesis and properties of a bridged phenalenone incorported into bicyclo[3.2.2]nonane skeleton. 6,9-dihydro-6,9-ethenocyclohepta[gh]phenalen-1-one |
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Authors: | Yoshikazu Sugihara Katsuhiro Hashimoto Masahiro Yoshiakwa Ichiro Murata |
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Institution: | Department of Chemistry, Faculty of Science, Osaka University, Toyonaka, Osaka 560, Japan |
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Abstract: | 6,9-Dihydro-6,9-ethenocycloheptagh]phenalen-1-one () has been synthesised starting from the Diels-Alder adduct () of acepleiadiene () and maleic anhydride through 10 steps with reasonable yields. Spectroscopic properties of suggestged the intramolecular electron supply from the remote ethylenes to the phenalenone π-systems in the ground-state of this molecule. |
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