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Functionalized 2-azabicyclo[3.3.1]nonanes. III.1 reductive rearrangement of an hexahydro-2-oxopyrano[3,2-b]pyridine
Authors:Joan Bosch  Josep Bonjoch  Isabel Serret
Affiliation:Department of Organic Chemistry, Faculty of Pharmacy, University of Barcelona, Barcelona-28 Spain
Abstract:Reduction of 5-benzoyl-8-methyl-2-oxo-3,4,4a,5,6,7-hexahydro-2H-pyrano[3,2-b] pyridine (1) with lithium aluminium hydride afforded (1R*,5S*,6R*,9S*)-2-benzyl-5-methyl-2-azabicyclo[3.3.1]nonane-6,9-diol (2).
Keywords:
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