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A new synthesis of d1-coriolin A. Application of a new SN2 reaction at a neopentylic position |
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| Authors: | Toshio Ito Nobuya Tomiyoshi Koki Nakamura Shizuo Azuma Makoto Izawa Fumio Maruyama Mitsutoshi Yanagiya Haruhisa Shirahama Takeshi Matsumoto |
| Institution: | Department of Chemistry, Faculty of Science, Hokkaido University Sapporo, 060 Japan |
| Abstract: | Dicyclopentadiene has been stereoselectively converted to a key tricyclic intermediate for the total synthesis of coriolin, through a route which involves a new SN2 reaction at a neopentylic position. |
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